ISOLATION AND CHARACTERIZATION OF THE MOLYBDENUM ALKYLIDYNE COMPLEX [(F3C)ME(2)CO]MO-2(C-T-BU)[N(AR)P=C(H)(CME(2)PH)] AND ITS CONVERSION TOA PHOSPHAMOLYBDACYCLOBUTENE

Authors
JAMISON GM SAUNDERS RS WHEELER DR ALAM TM MCCLAIN MD LOY DA ZILLER JW
Citation
Gm. Jamison et al., ISOLATION AND CHARACTERIZATION OF THE MOLYBDENUM ALKYLIDYNE COMPLEX [(F3C)ME(2)CO]MO-2(C-T-BU)[N(AR)P=C(H)(CME(2)PH)] AND ITS CONVERSION TOA PHOSPHAMOLYBDACYCLOBUTENE, Organometallics, 15(15), 1996, pp. 3244-3246
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
15
Year of publication
1996
Pages
3244 - 3246
Database
ISI
SICI code
0276-7333(1996)15:15<3244:IACOTM>2.0.ZU;2-X
Abstract
Novel molybdenum alkylidyne [(F3C)Me(2)-CO]Mo-2(C-t-Bu)[N(Ar)P=C(H)(CM e(2)Ph)] (Ar = 2,6-(i-Pr)(2)C6H3; 3b) is formed in the reaction of ter t-butylphosphaalkyne 2 with molybdenum alkylidene 1b. Alkylidyne 3b, w hich contains a formal (phosphaalkenyl)amido ligand, rearranges quanti tatively at elevated temperature to form the alkoxide-shifted phospham olybdacyclobutene 4b. Complexes 3b and 4b have been fully characterize d by spectroscopic and X-ray crystallographic analysis; cleavage of th e P=C-t-Bu triple bond in complex 3b is confirmed.