ANALYSIS OF STEREOCHEMICAL NONRIGIDITY IN 5-COORDINATE CYCLOPENTADIENYLMETAL COMPLEXES BY THE STRUCTURE CORRELATION METHOD

Authors
SMITH JM COVILLE NJ
Citation
Jm. Smith et Nj. Coville, ANALYSIS OF STEREOCHEMICAL NONRIGIDITY IN 5-COORDINATE CYCLOPENTADIENYLMETAL COMPLEXES BY THE STRUCTURE CORRELATION METHOD, Organometallics, 15(15), 1996, pp. 3388-3392
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
15
Year of publication
1996
Pages
3388 - 3392
Database
ISI
SICI code
0276-7333(1996)15:15<3388:AOSNI5>2.0.ZU;2-V
Abstract
The intramolecular cis/trans isomerization mechanism of solid-state ps eudo-five-coordinate complexes of the type CpML(4) was examined by the structure correlation technique, and the data revealed that the mecha nism most likely proceeds via a combined Berry-turnstile mechanism.