PHOTOINDUCED CYCLOADDITIONS AND CYCLIZATIONS - MECHANISTIC STUDIES AND SYNTHETIC APPLICATIONS

Authors
MATTAY J ALBRECHT E FAGNONI M HEIDBREDER A HINTZ S KIRSCHBERG T KLESSINGER M MAHLMANN J SCHLACHTER I STEENKEN S
Citation
J. Mattay et al., PHOTOINDUCED CYCLOADDITIONS AND CYCLIZATIONS - MECHANISTIC STUDIES AND SYNTHETIC APPLICATIONS, Journal of information recording, 23(1-2), 1996, pp. 23-29
Citations number
28
Categorie Soggetti
Photographic Tecnology","Material Science
Journal title
Journal of information recording → ACNP
ISSN journal
10256008
Volume
23
Issue
1-2
Year of publication
1996
Pages
23 - 29
Database
ISI
SICI code
1025-6008(1996)23:1-2<23:PCAC-M>2.0.ZU;2-X
Abstract
Synthetic applications and mechanistic studies from three areas of pho toinduced cycloadditions and cyclizations are reported: First it is sh own that unsaturated silyl enol ethers preferentially cyclisize in a 6 -endo mode via their photochemically generated radical cations. In the following chapter we discuss fragmentation-cyclization reactions of u nsaturated alpha-cyclopropyl ketones by photoinduced electron transfer leading to polycyclic compounds. Finally a kinetic and theoretical st udy of [2+3] cycloadditions of nitrile ylides generated from 2H-azirin es is presented.