QUANTUM-CHEMICAL MODELING OF THE PHOTOLYSIS OF 2,5-DIPHENYLOXAZOLE

Authors
MAIER GV BAZYL OK ARTYUKHOV VY
Citation
Gv. Maier et al., QUANTUM-CHEMICAL MODELING OF THE PHOTOLYSIS OF 2,5-DIPHENYLOXAZOLE, High energy chemistry, 30(4), 1996, pp. 253-256
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
High energy chemistry → ACNP
ISSN journal
00181439
Volume
30
Issue
4
Year of publication
1996
Pages
253 - 256
Database
ISI
SICI code
0018-1439(1996)30:4<253:QMOTPO>2.0.ZU;2-Y
Abstract
The photochemical opening of an oxazole ring in a molecule of 2,5-diph enyloxazole was studied by quantum-chemical methods. The protic medium is involved in photolysis of this compound with cleavage of the O-C b ond in the oxazole ring. Photolysis proceeds predominantly via the pi sigma triplet state localized on this bond.