T. Kauly et al., HIGHLY FILLED THERMOPLASTIC COMPOSITES .2. EFFECTS OF PARTICLE-SIZE DISTRIBUTION ON SOME PROPERTIES, Polymer composites, 17(6), 1996, pp. 806-815
The effect of irregularly shaped glass particle size and size distribu
tion on the packing density and flexural mechanical properties of high
ly-filled composites with a rubbery thermoplastic matrix was studied.
Increasing the particle's median size and size distribution width sign
ificantly increases the packing density of the composites. Compression
molding causes the glass particles to fracture at a decreasing level
with an increasing distribution width. Particle median size, rather th
an size distribution, affects the mechanical properties; The flexural
modulus and strength increase and the ultimate deflection in flexure d
ecreases with a decreasing median size. A ''glass network'' is formed
in the compression molded composites because of the mechanical interlo
cking of particles. The nature of this continuous glass phase predomin
ates the composites mechanical behavior. The particle's size and shape
determine the nature of the glass network and, thus, have a dominatin
g effect on the mechanical properties. The latter are significantly af
fected by the particle's surface properties. A specific silane treatme
nt of the glass particles acts to reduce the particle/particle frictio
n, resulting in a higher packing density. The treatment also acts as a
cohesive liquid to increase the strength of the glass network, and to
increase the particle/polymer adhesion, increasing the composites' st
rength and ductility.