In this work, poly ether ketone ether ketone ketone (PEKEKK) was used
as a thermoplastic adhesive for joining metals. Titanium and cobalt ch
romium alloys were joined to form tensile butt joints. These tensile s
pecimens were used to evaluate bond performance. A controlled thermal
processing cycle was used to modify and enhance the polymer crystallin
ity during bonding. The resulting effects on bond performance were exa
mined. The process window for a thermal bonding process was identified
. Factorial experiments were conducted to determine the effects of mod
ifications to adhesive and adherend material, and bonding pressure on
bond performance. A titanium alloy and a cobalt chromium alloy were us
ed as the adherends. Understanding changes in the thermoplastic adhesi
ve joint with the variation of process parameters will allow for prope
r application and processing of thermoplastic structural adhesives.