R. Beyreuther et R. Vogel, SPINNABILITY OF POLYMER MELTS - A COMPLEX PROBLEM IN BASIC RESEARCH, International polymer processing, 11(2), 1996, pp. 154-158
Melt spinning of polymer melts is a formation process making extremely
high demands on the material's continuous deformation ability by high
est deformation speeds. The structural conditions of a thermoplastic p
olymer which are necessary for spinnability have not been exactly clea
red up yet. But this knowledge gap must be closed especially with rega
rd to the many efforts to spin fibers with new properties made from mo
dified polymers of polymer blends. The article is begun with a pragmat
ic definition of the spinnability of a polymer melt. The discussion of
a structural rheological model shows a correlation between dynamic rh
eological measurement datas of polymer melts and experimental experien
ce about their spinnability. Proceeding from a comprehensive descripti
on of possible failure cases (fiber beak problems), results of rheolog
ical measurement of a number of different polymers, which are spinnabl
e well, not as well or not at all, are compared. The article is conclu
ded by some comments on open problems which have to be solved by basic
research in the near future.