Uw. Grummt et al., CHEMICAL-DEPOSITION OF SILVER NANOCLUSTERS ON SELF-ASSEMBLED ORGANIC MONOLAYERS - A STRATEGY TO CONTACT INDIVIDUAL MOLECULES, Chemical physics letters, 263(3-4), 1996, pp. 581-584
Self-assembled monolayers (SAMs) on gold(111) surfaces were prepared c
onsisting of a matrix of n-dodecane thiol and a mercaptan as a host wh
ich is terminated by a four-electron reducing agent. Upon treatment wi
th ammoniated silver nitrate solutions silver nanoclusters am generate
d on the SAM surface. Physical development allows enlargement of the c
lusters.