For the design of novel acid catalysts it is Important to understand t
he principles of the generation of acidity. However, the origin of thi
s acidity is unclear because the mixed solid-acid usually possesses a
complicated structure leading to different types of sites. The CVD of
silica is being used on high surface area basic oxides to provide mode
l compounds to elucidate the formation and functioning of acid catalys
ts. This paper reviews these studies and also shows how novel heat res
istant catalysts can be obtained.