Ns. Shastina et al., ASYMMETRICALLY SUBSTITUTED MYOINOSITOLS . 38. SYNTHESIS OF PHOSPHATIDYLINOSITYL GLUCOSIDE, Bioorganiceskaa himia, 22(6), 1996, pp. 446-450
The total synthesis of spho)-4(6)-O-beta-D-glucopyranosyl-sn-myo-inosi
tol was performed. The major stages of the synthetic route are glycosy
lation of the substituted myo-inositol derivative by the glycosyl fluo
ride method and creation of the phosphorus moiety of the target glycol
ipid by means of the H-phosphonate technique.