Thermal and pulling conditions have been optimized in a laboratory Czo
chralski apparatus to yield optically homogeneous crystals of hexagona
l Pb5GeO4(VO4)(2). The wavelength dependence of absorption coefficient
was calculated from transmission and reflection measurements in the v
isible region. A hypothesis regarding the zone structure in connection
to the fundamental absorption edge was raised and the bandgap width c
orresponding to indirect transition at room temperature was determined
from the alpha(1/2)-hv curve.