Since poly (ethylene naphtalene-2,6-dicarboxylate) (PEN) gives high pe
rformance films with key properties superior to those of PET polyester
films, it has been argued that it could be used as a substitute for t
he latter in a large number of applications. In this paper more inform
ation on the electrical properties of this material are given and comp
ared to those of PET. These properties, i.e. complex permittivity and
breakdown voltage, are investigated under controlled and uncontrolled
environments and before and after thermal ageing at a temperature 60 d
egrees C higher than the thermal rating of each material.