DETERMINATION OF THE PARTICLE-SIZE DISTRIBUTION OF LATEX USING A COMBINATION OF ELASTIC LIGHT-SCATTERING AND TURBIDIMETRY - A SIMULATION STUDY

Citation
G. Elicabe et G. Frontini, DETERMINATION OF THE PARTICLE-SIZE DISTRIBUTION OF LATEX USING A COMBINATION OF ELASTIC LIGHT-SCATTERING AND TURBIDIMETRY - A SIMULATION STUDY, Journal of colloid and interface science, 181(2), 1996, pp. 669-672
Citations number
10
Categorie Soggetti
Chemistry Physical
ISSN journal
00219797
Volume
181
Issue
2
Year of publication
1996
Pages
669 - 672
Database
ISI
SICI code
0021-9797(1996)181:2<669:DOTPDO>2.0.ZU;2-R
Abstract
Turbidimetry at several wavelengths and elastic light scattering (ELS) at several angles can be used to determine particle size distribution s (PSDs) of suspended particles using Mie scattering theory. The limit ed range of measurement in reciprocal space and the measurement noise always cause both techniques to have their own limitations. In this wo rk, a way to combine turbidimetry and ELS data to be processed togethe r is proposed. In order to investigate the convenience of simultaneous versus individual processing, a set of computationally generated expe riments performed on suspensions of polystyrene particles is analyzed. The results clearly show that when the data are jointly processed the quality of the PSDs obtained is highly superior, This fact can be exp lained by the complementary characteristics of both techniques. Turbid imetry is more accurate at larger sizes, whereas ELS gives more precis e estimations at smaller sizes. This work shows that simultaneous proc essing of experimental data from different sources seems to be a valid alternative for improving the quality of indirect measurements. (C) 1 996 Academic Press, Inc.