M. Sikovec et al., APPLICATION OF THERMAL LENS SPECTROMETRIC DETECTION TO THE DETERMINATION OF HEAVY-METALS BY ION CHROMATOGRAPHY, Journal of chromatography, 739(1-2), 1996, pp. 111-117
Citations number
18
Categorie Soggetti
Chemistry Analytical","Biochemical Research Methods
Dual-beam thermal lens spectrometry (TLS) was tested as a potential de
tection technique after the ion chromatographic separation of some hea
vy metals. Before detection, heavy metal ions of interest (Cu2+, Ni2+,
Co2+, Zn2+, Cd2+, Pb2+, Fe2+ and Fe3+) were separated on a Dionex HPI
C-CSS separation column. For the Separation of Cu2+, Ni2+, Co2+, Zn2+,
Pb2+ and Cd2+, oxalic acid was added to form anionic and cationic met
al complexes, which were then separated on the same column. For the se
paration of Fe2+ and Fe3+, pyridine-2,6-dicarboxylic acid was added to
the eluent and iron species were separated as anions. 4-(2-Pyridylazo
)resorcinol was used as a postcolumn reagent to form absorbing metal c
omplexes characterized by an absorption maximum at 520 nm. For Cu2+ an
d Co2+ ions, TLS detection at 514.5 nm was found to be advantageous co
mpared with UV-Vis detection at 520 nm (lambda(max) = 520 nm), whereas
for Zn2+ and Ni2+ the detection limits of the two techniques were com
parable.