HEXA-O-ACETYL-D-GENTIOBIAL IN ENANTIOSELECTIVE SYNTHESIS OF LYSOCEREBROSIDES AND THEIR CONJUGATES

Authors
TOLSTIKOV AG TOLSTIKOVA OV TOLSTIKOV GA
Citation
Ag. Tolstikov et al., HEXA-O-ACETYL-D-GENTIOBIAL IN ENANTIOSELECTIVE SYNTHESIS OF LYSOCEREBROSIDES AND THEIR CONJUGATES, Mendeleev communications, (4), 1996, pp. 128-130
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
4
Year of publication
1996
Pages
128 - 130
Database
ISI
SICI code
0959-9436(1996):4<128:HIESOL>2.0.ZU;2-0
Abstract
Hexa-O-acetyl-D-gentiobial 1 and its decyclization product tetra-O-ace tyl-beta-D-glucopyranosyloxy)hex-2-enal 2 have been used to synthesize O-glycosylated aminodiols 9, 10, 15 that model the structure of natur al lysocerebrosides. Compounds 9, 10, 15 can serve as basic components to produce N-acylated conjugates with derivatives of arachidonic and glycyrrhizic acids.