Ag. Tolstikov et al., HEXA-O-ACETYL-D-GENTIOBIAL IN ENANTIOSELECTIVE SYNTHESIS OF LYSOCEREBROSIDES AND THEIR CONJUGATES, Mendeleev communications, (4), 1996, pp. 128-130
Hexa-O-acetyl-D-gentiobial 1 and its decyclization product tetra-O-ace
tyl-beta-D-glucopyranosyloxy)hex-2-enal 2 have been used to synthesize
O-glycosylated aminodiols 9, 10, 15 that model the structure of natur
al lysocerebrosides. Compounds 9, 10, 15 can serve as basic components
to produce N-acylated conjugates with derivatives of arachidonic and
glycyrrhizic acids.