THE PALLADIUM-MEDIATED CONVERSION OF 1,6-DIAZACYCLODECA-3,8-DIYNES TO3,3'-BISPYRROLES - AN UNEXPECTED REORGANIZATION OF AN ALKYNE PI-SYSTEM

Authors
GLEITER R RITTER J
Citation
R. Gleiter et J. Ritter, THE PALLADIUM-MEDIATED CONVERSION OF 1,6-DIAZACYCLODECA-3,8-DIYNES TO3,3'-BISPYRROLES - AN UNEXPECTED REORGANIZATION OF AN ALKYNE PI-SYSTEM, Tetrahedron, 52(31), 1996, pp. 10383-10388
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
31
Year of publication
1996
Pages
10383 - 10388
Database
ISI
SICI code
0040-4020(1996)52:31<10383:TPCO1T>2.0.ZU;2-7
Abstract
The Pd-catalyzed rearrangement of ropyl-1,6-diisopropyl-1,6-diazacyclo deca-3,8-diyne (1b) to N,N'-diisopropyl-3,3'-bispyrrole (2b) in a one pot reaction involves forming two new C-C bonds, cleaving one triple b ond, two allylic rearrangements and two dehydrogenation steps. Copyrig ht (C) 1996 Elsevier Science Ltd