TRIAZOLOPYRIDINES .17. N2-DICYANOMETHYLIDES - SYNTHESIS, STRUCTURE AND REACTIVITY WITH ACETYLENIC DIPOLAROPHILES

Authors
ABARCA B BALLESTEROS R MUNOZ A JONES G
Citation
B. Abarca et al., TRIAZOLOPYRIDINES .17. N2-DICYANOMETHYLIDES - SYNTHESIS, STRUCTURE AND REACTIVITY WITH ACETYLENIC DIPOLAROPHILES, Tetrahedron, 52(31), 1996, pp. 10519-10524
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
31
Year of publication
1996
Pages
10519 - 10524
Database
ISI
SICI code
0040-4020(1996)52:31<10519:T.N-SS>2.0.ZU;2-R
Abstract
Preparation and structure of 1,2,3-triazolo[1,5-a]pyridinium N2-dicyan omethylides 7a,b are described. Reaction with methyl propiolate gives trisubstituted indolizines 8a,b in good yield. Reaction of 7b with dim ethyl acetylenedicarboxylate gives a quinolizine 12. Copyright (C) 199 6 Elsevier Science Ltd