AROMATIC 3-AZA-COPE REARRANGEMENT OVER ZEOLITES

Citation
R. Sreekumar et R. Padmakumar, AROMATIC 3-AZA-COPE REARRANGEMENT OVER ZEOLITES, Tetrahedron letters, 37(30), 1996, pp. 5281-5282
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
37
Issue
30
Year of publication
1996
Pages
5281 - 5282
Database
ISI
SICI code
0040-4039(1996)37:30<5281:A3ROZ>2.0.ZU;2-7
Abstract
N-Allyl-2-methyl aniline 1a], N-allyl and N-(2'-methyl allyl)-N-methyl anilines [1b & 1c, respectively] undergo the 3-aza-Cope rearrangement in presence of HY-Zeolite, HEMT and HZeolite beta in hexane at 80 deg rees C to give Indoline derivatives as the major product. Copyright (C ) 1996 Elsevier Science Ltd