DEBENZYLATION OF COMPLEX OLIGOSACCHARIDES USING FERRIC-CHLORIDE

Authors
RODEBAUGH R DEBENHAM JS FRASERREID B
Citation
R. Rodebaugh et al., DEBENZYLATION OF COMPLEX OLIGOSACCHARIDES USING FERRIC-CHLORIDE, Tetrahedron letters, 37(31), 1996, pp. 5477-5478
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
31
Year of publication
1996
Pages
5477 - 5478
Database
ISI
SICI code
0040-4039(1996)37:31<5477:DOCOUF>2.0.ZU;2-V
Abstract
Anhydrous FeCl3 in CH2Cl2 at room temperature and 0 degrees C has been used to debenzylate monosaccharides and oligosaccharides in yields ge nerally greater than 70%. Notably, alkenes, acetates, benzoates, phtha limides, acyl amides, and sensitive glycosidic linkages are unaffected by the reaction conditions. Copyright (C) 1996 Elsevier Science Ltd