STEREOSELECTIVE SYNTHESIS OF THE BICYCLIC CORE STRUCTURE OF THE HIGHLY OXIDIZED SESQUITERPENE NEOLIACINIC ACID

Authors
CLARK JS DOSSETTER AG WHITTINGHAM WG
Citation
Js. Clark et al., STEREOSELECTIVE SYNTHESIS OF THE BICYCLIC CORE STRUCTURE OF THE HIGHLY OXIDIZED SESQUITERPENE NEOLIACINIC ACID, Tetrahedron letters, 37(31), 1996, pp. 5605-5608
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
31
Year of publication
1996
Pages
5605 - 5608
Database
ISI
SICI code
0040-4039(1996)37:31<5605:SSOTBC>2.0.ZU;2-Q
Abstract
The bicyclic core (3) of the sesquiterpene neoliacinic acid (1) has be en constructed in a stereoselective manner by [2,3]-sigmatropic ring-e xpansion of an oxonium ylide generated catalytically from the alpha-di azo ketone 4. Copyright (C) 1996 Elsevier Science Ltd