CHRONOPOTENTIOMETRY WITH AN ALTERNATING-CURRENT AT CYLINDRICAL MICROELECTRODES

Authors
MOLINA A RUIZ R MARTINEZORTIZ F LOPEZTENES M
Citation
A. Molina et al., CHRONOPOTENTIOMETRY WITH AN ALTERNATING-CURRENT AT CYLINDRICAL MICROELECTRODES, Collection of Czechoslovak Chemical Communications, 61(7), 1996, pp. 973-984
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
61
Issue
7
Year of publication
1996
Pages
973 - 984
Database
ISI
SICI code
0010-0765(1996)61:7<973:CWAAAC>2.0.ZU;2-M
Abstract
A theoretical study on the application of the first cycle of alternati ng current to cylindrical microelectrodes is presented. The analytical expressions obtained here are applicable to electrodes with radii of up to 50 mu m, which are in the range of ''large'' microelectrodes. A method for determination of the kinetic parameter k(s) independently o f alpha and methods for calculation of E(0) are proposed.