SYNTHESIS OF CHIRAL ALLYLIC ALCOHOLS BY THE REACTION OF CHIRAL TITANIUM-ALKYNE COMPLEXES WITH CARBONYL-COMPOUNDS

Authors
TAKAYANAGI Y YAMASHITA K YOSHIDA Y SATO F
Citation
Y. Takayanagi et al., SYNTHESIS OF CHIRAL ALLYLIC ALCOHOLS BY THE REACTION OF CHIRAL TITANIUM-ALKYNE COMPLEXES WITH CARBONYL-COMPOUNDS, Chemical communications, (15), 1996, pp. 1725-1726
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
15
Year of publication
1996
Pages
1725 - 1726
Database
ISI
SICI code
1359-7345(1996):15<1725:SOCAAB>2.0.ZU;2-#
Abstract
Chiral titanium-alkyne complexes derived from chloro-tris[(-)-menthoxy ]titanium/2 (PrMgCl)-Mg-i and alkynes react with aldehydes to afford o ptically active allylic alcohols in up to 38% ee.