FIRST EXAMPLE OF A RIGID (MU-OXO-DI-MU-ACETATO)DIIRON(III) COMPLEX WITH 1,2-BIS[2-DI(2-PYRIDYL)METHYL-6-PYRIDYL]ETHANE - ITS EFFICIENT CATALYSIS FOR FUNCTIONALIZATION OF ALKANES
M. Kodera et al., FIRST EXAMPLE OF A RIGID (MU-OXO-DI-MU-ACETATO)DIIRON(III) COMPLEX WITH 1,2-BIS[2-DI(2-PYRIDYL)METHYL-6-PYRIDYL]ETHANE - ITS EFFICIENT CATALYSIS FOR FUNCTIONALIZATION OF ALKANES, Chemical communications, (15), 1996, pp. 1737-1738
The mu-oxo-di-mu-acetatodiiron(III) complex [Fe-2(hexpy)(O)-(OCOMe)(2)
][ClO4](2) (hexpy = 1,2-bis [2-di(2-pyridyl)methyl-6-pyridyl]ethane) e
fficiently catalyses the oxygenation of cyclohexane, methylcyclohexane
and adamantane in the presence of m-chloroperbenzoic acid.