END-ON BONDING OF A TE-3(2-) POLYTELLURIDE CHAIN TO A TRANSITION-METAL FRAGMENT - SYNTHESIS AND STRUCTURE OF RYPT)](2)[CR(CO)(5)TE-3]CENTER-DOT-0.5C(2)N(2)H(8) AND [K(2,2,2-CRYPT)](2)[(CR(CO)(5))TE-2(2)]

Authors
STAUF S REISNER C TREMEL W
Citation
S. Stauf et al., END-ON BONDING OF A TE-3(2-) POLYTELLURIDE CHAIN TO A TRANSITION-METAL FRAGMENT - SYNTHESIS AND STRUCTURE OF RYPT)](2)[CR(CO)(5)TE-3]CENTER-DOT-0.5C(2)N(2)H(8) AND [K(2,2,2-CRYPT)](2)[(CR(CO)(5))TE-2(2)], Chemical communications, (15), 1996, pp. 1749-1750
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
15
Year of publication
1996
Pages
1749 - 1750
Database
ISI
SICI code
1359-7345(1996):15<1749:EBOATP>2.0.ZU;2-6
Abstract
The reaction of K2Te4 with different stoichiometries of [Cr(CO)(6)] an d 2,2,2-crypt ,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) in en (ethylenediamine) gives dark brown plates of [K(2,2,2-crypt)](2)[Cr(C O)(5)Te-3]. 0.5C(2)N(2)H(8) and orange needles of [K(2,2,2-crypt)](2)[ {Cr(CO)5}Te-2(2)] which are characterized by X-ray crystallography and IR spectroscopy.