THE INFLUENCE OF LIGAND BITE ANGLE ON THE ENANTIOSELECTIVITY OF COPPER(II)-CATALYZED DIELS-ALDER REACTIONS

Authors
DAVIES IW GERENA L CASTONGUAY L SENANAYAKE CH LARSEN RD VERHOEVEN TR REIDER PJ
Citation
Iw. Davies et al., THE INFLUENCE OF LIGAND BITE ANGLE ON THE ENANTIOSELECTIVITY OF COPPER(II)-CATALYZED DIELS-ALDER REACTIONS, Chemical communications, (15), 1996, pp. 1753-1754
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
15
Year of publication
1996
Pages
1753 - 1754
Database
ISI
SICI code
1359-7345(1996):15<1753:TIOLBA>2.0.ZU;2-3
Abstract
Novel spirobis(oxazolines) provide excellent levels of stereocontrol i n copper-catalysed Diels-Alder reactions; the larger the ligand bite a ngle the higher the enantioselection (up to 98.4% ee).