SYNTHESIS OF DIPROPARGYLPHENYLAMINE POLYM ERS

Cyclopolymerization of dipropargylphenylamine was studied in the prese nce of weak electron sigma-acceptor CBr4. The triple bond was activate d thermally or by photoexcitation of donor-acceptor complex. This lead s to the salt of quaternary iminium containing a triple bond conjugate d with pi-system of aromatic nucleus and able to undergo thermal ol ph otoinduced polymerization to form a cyclic polyconjugated polycation. Complex formation of dipropargylphenylamine with CBr4 was studied, and it was shown that it is possible to use light-sensitive compositions based on these complexes in the processes of information recording.