REVERSIBLE PHOTODISSOCIATION OF MO(CO)(6) IN A ZEOLITE CAGE

Authors
YOKOTA T YAGINUMA M KONDO JN DOMEN K HIROSE C WAKABAYASHI F
Citation
T. Yokota et al., REVERSIBLE PHOTODISSOCIATION OF MO(CO)(6) IN A ZEOLITE CAGE, Catalysis letters, 40(1-2), 1996, pp. 89-94
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
40
Issue
1-2
Year of publication
1996
Pages
89 - 94
Database
ISI
SICI code
1011-372X(1996)40:1-2<89:RPOMIA>2.0.ZU;2-8
Abstract
Photodissociation of Mo(CO)(6) in a NaY zeolite was studied under vacu um and CO atmosphere by FTIR. The stepwise CO-dissociation under vacuu m proceeded to form Mo(CO)(3) via Mo(CO)(5) and Mo(CO)(4). The Mo(CO)( 6) was regenerated by introduction of CO to Mo(CO)(3). Irradiation und er gaseous CO favored the formation of Mo(CO)(4).