[OS-5(MU-H)(2)(CO)(16)] - A 2ND CRYSTAL FORM

Authors
LEONG WK EINSTEIN FWB POMEROY RK
Citation
Wk. Leong et al., [OS-5(MU-H)(2)(CO)(16)] - A 2ND CRYSTAL FORM, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1607-1609
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
7
Pages
1607 - 1609
Database
ISI
SICI code
0108-2701(1996)52:<1607:[-A2CF>2.0.ZU;2-C
Abstract
The title compound, hexadecacarbonyl-1 kappa(3)C, 2 kappa(3)C,-3 kappa (3) C, 4 kappa(4) C, 5 kappa(3) C-di-mu-hydrido-1:2 kappa(2)H; 1:3 kap pa(2)H-pentaosmium(8 Os-Os), has been crystallized in a different crys tal form from that reported previously [Guy & Sheldrick (1978). Acta C ryst. B34, 1725-1727]. The form reported here has crystallographic mir ror symmetry and the packing arrangement in the crystal exhibits a dif ferent relative orientation of the molecules from the earlier structur e.