S(1-PHENYL-1,3-HEXANEDIONATO-O,O')OXOVANADIUM(IV), [VO(C27H28N2O5)]

Authors
HOPE H BORER LL
Citation
H. Hope et Ll. Borer, S(1-PHENYL-1,3-HEXANEDIONATO-O,O')OXOVANADIUM(IV), [VO(C27H28N2O5)], Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1621-1624
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
7
Pages
1621 - 1624
Database
ISI
SICI code
0108-2701(1996)52:<1621:S[>2.0.ZU;2-H
Abstract
Schiff base ligands derived from triketones form stable complexes with VO. In the mononuclear vanadyl complex of ,3-propandiyldiamino)bis(1- phenyl-1,3-hexanedione, vanadium is five-coordinate, equatorially bond ed to four carbonyl O atoms in a nearly square-planar arrangement and axially to one other O atom. N atoms are not involved in complex forma tion. The hydroxy group is disordered.