R. Rudert et G. Czichocki, SODIUM 1,12-DODECYLENE DISULFATE HYDRATE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1670-1673
There are two independent dodecylene disulfate molecules in the crysta
l of 2Na(+).Cl(1)2H(24)O(8)S(2)(2-).2/3H(2)O, one with a centrosymmetr
ic conformation, its center lying on a crystallographic center of symm
etry, the second with an asymmetric conformation, which is partially d
isordered. The molecules form a layer structure parallel to the ab pla
ne, the polar parts of neighbouring molecular layers connecting via co
ordination to the Na+ ion. Additionally, there are hydrogen bonds betw
een the water molecule and two sulfate groups.