It is now clear that there is a substantial population of primordial b
inaries in Galactic globular clusters and that binary interactions are
a major influence on globular cluster evolution. Collisional interact
ions involving stars in binaries may provide a significant channel for
the formation of various stellar exotica, such as blue stragglers, X-
ray binaries and millisecond pulsars. We report on an extensive series
of numerical experiments of binary-binary scattering, analysing the c
ross-section for close approach during interactions for a range of har
d binary parameters of interest in globular cluster cores. We consider
the implied rate for tidal interactions for different globular cluste
rs and compare our results with previous, complementary estimates of s
tellar collision rates in globular clusters. We find that the collisio
n rate for binary-binary encounters dominates in low-density clusters
if the binary fraction in the cluster is larger than 0.2 for wide main
-sequence binaries. In dense clusters, binary-single interactions domi
nate the collision rate and the core binary fraction must be less than
or similar to 0.1 per decade in semimajor axis, or too many collision
s take place compared with observations. The rates are consistent if b
inaries with semimajor axes similar to 100 au are overabundant in low-
density clusters, or if breakup and ejection substantially lower the b
inary fraction in denser clusters. Given reasonable assumptions about
fractions of binaries in the cores of low-density clusters such as NGC
5053, we cannot account for all the observed blue stragglers by stell
ar collisions during binary encounters, suggesting that a substantial
fraction may be due to coalescence of tight primordial binaries.