EFFICIENT SYNTHESIS OF A CARBOCYCLIC CORE MOIETY WITH THE STEREOCHEMISTRY OF THE C-1027 CHROMOPHORE

Authors
SATO I AKAHORI Y IIDA K HIRAMA M
Citation
I. Sato et al., EFFICIENT SYNTHESIS OF A CARBOCYCLIC CORE MOIETY WITH THE STEREOCHEMISTRY OF THE C-1027 CHROMOPHORE, Tetrahedron letters, 37(29), 1996, pp. 5135-5138
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
29
Year of publication
1996
Pages
5135 - 5138
Database
ISI
SICI code
0040-4039(1996)37:29<5135:ESOACC>2.0.ZU;2-W
Abstract
A stereoselective and concise route to the bicyclo[7.3.0]dodecadiyne c ore moiety (26) of the C-1027 chromophore (1) through highly efficient LiN(TMS)(2)/CeCl3-mediated cyclization of alkynyl aldehyde 24 has bee n established. Copyright (C) 1996 Elsevier Science Ltd