T. Czerniawski et Z. Wojtczak, DETERMINATION OF THE INITIATION RATE IN THE POLYMERIZATION OF ZINC, COBALT AND NICKEL ACRYLATES, European Polymer Journal, 32(8), 1996, pp. 1035-1036
Results for the determination of the initiation rate of polymerization
reaction of zinc, cobalt and nickel acrylates, initiated by 2,2'-azob
isisobutyronitryle in dimethylformamide at different temperatures are
reported. The inhibition method involving the stable radical N,N-diphe
nyl-N'-picrylhydrazyl has been used. The initiation rate constants 2k(
d)f and activation energy of initiation E(2kdf) have been determined.
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