We present the results of spectroscopic studies on GaN based epitaxial
materials on SiC substrates by metalorganic chemical vapor deposition
. A variety of techniques has been used to study the optical propertie
s of GaN epilayers and GaN/AlGaN heterostructures. Sharp spectral stru
ctures associated with the intrinsic free excitons were observed by ph
otoluminescence and reflectance measurements from GaN based materials
grown on SiC substrates. The residual strain was found to have a stron
g influence in determining the energies of exciton transitions. Picose
cond relaxation studies of exciton decay dynamics suggest that an AlGa
N cladding layer with a small mole fraction of AIN can be relatively e
ffective in enhancing the radiative recombination rate for excitons by
reducing the density of dislocations and suppressing surface recombin
ation velocity in the GaN active layer for the GaN/AlGaN heterostructu
re samples. (C) 1996 American Institute of Physics.