Sg. Hong et al., THE EFFECTS OF A SLUSHING OIL ON THE CURING AND DEGRADATION BEHAVIOR OF AN OIL-ACCOMMODATING EPOXY ADHESIVE, Die Angewandte makromolekulare Chemie, 238, 1996, pp. 129-141
The effect of aliphatic slushing oil on the curing and degradation beh
avior of an oil-accommodating epoxy adhesive is studied by using diffe
rential scanning calorimetry (DSC), Fourier transform infrared spectro
scopy (FTIR), and thermogravimetric analysis (TGA). The results of FTI
R and DSC indicate that the curing rate of the tested epoxy system is
little affected in the presence of the oil. However, the decrease of t
he curing exotherm accompanied with a broadening of the glass transiti
on confirms that the oil can affect the curing mechanisms and may chan
ge the structure of the cured resin. Additionally, it is evident from
the TGA results that the thermal resistance of the resin deteriorates
in the presence of the oil, which is attributed to the changes in the
structure and the degradation mechanism of the epoxy system.