CYCLOADDITION OF MOORE KETENE TO 4-SUBSTITUTED STYRENES

Authors
GHEORGHIU MD PARVULESCU L DRAGHICI C MIHAI M POPESCU A
Citation
Md. Gheorghiu et al., CYCLOADDITION OF MOORE KETENE TO 4-SUBSTITUTED STYRENES, Revue Roumaine de Chimie, 41(3-4), 1996, pp. 283-289
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
41
Issue
3-4
Year of publication
1996
Pages
283 - 289
Database
ISI
SICI code
0035-3930(1996)41:3-4<283:COMKT4>2.0.ZU;2-8
Abstract
Products of the reaction of t-butylcyanoketene (TBCK, Moore's ketene) with 4-nitro-, 4-methoxy-, 4-fluoro- and 4-chlorostyrene are presented . Based on the analysis of reaction products we propose a stepwise rea ction mode for the cases of 4-methoxy, 4-fluoro- and 4-chlorostyrene; 4-nitrostyrene reacted in a (2) pi(s) + (2) pi(a) concerted mode.