The crystallization kinetics of Fe-based amorphous alloys was investig
ated by differential thermal analysis (DTA) and differential scanning
calorimetry (DSC). Rather high values of activation energies were expl
ained as a result of simultaneously correlated displacements of groups
of atoms during the course of crystallization and allowed the correla
tion of amorphous alloys regarding their different composition. Connec
tions between the temperatures, activation energies and thermodynamic
driving forces were considered. Special attention was paid to the form
ation of nanocrystalline structures (Finemet).