DEHYDROGENATION OF 2-PICOLYL ALCOHOL TO PYRIDINE-2-CARBOXALDEHYDE OVER MODIFIED SILICO-ALUMINOPHOSPHATE CATALYSTS

Authors
RAO RR KULKARNI SJ SUBRAHMANYAM M RAO AVR
Citation
Rr. Rao et al., DEHYDROGENATION OF 2-PICOLYL ALCOHOL TO PYRIDINE-2-CARBOXALDEHYDE OVER MODIFIED SILICO-ALUMINOPHOSPHATE CATALYSTS, Applied catalysis. A, General, 142(2), 1996, pp. 191-196
Citations number
28
Journal title
Applied catalysis. A, General → ACNP
ISSN journal
0926860X
Volume
142
Issue
2
Year of publication
1996
Pages
191 - 196
Database
ISI
SICI code
0926-860X(1996)142:2<191:DO2ATP>2.0.ZU;2-G
Abstract
The dehydrogenation of 2-picolyl alcohol was carried out over modified and unmodified amorphous/crystalline silico-aluminophosphate catalyst s. The silico-aluminophosphates are mild and selective oxidation catal ysts. The best catalytic performance is shown by Sb-K-SAPO (DPA) with the formation of 81.9% pyridine-2-carboxaldehyde. Pyridine and 2-picol ine were also observed as byproducts.