PHOTOOXIDATION OF 2,2'-INDOLYLINDOLINES TO 2,2'-BIINDOLES - MILD FORMATION OF DITRYPTOPHAN CROSS-LINKS

Citation
Ds. Carter et Dl. Vanvranken, PHOTOOXIDATION OF 2,2'-INDOLYLINDOLINES TO 2,2'-BIINDOLES - MILD FORMATION OF DITRYPTOPHAN CROSS-LINKS, Tetrahedron letters, 37(32), 1996, pp. 5629-5632
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
37
Issue
32
Year of publication
1996
Pages
5629 - 5632
Database
ISI
SICI code
0040-4039(1996)37:32<5629:PO2T2->2.0.ZU;2-O
Abstract
2,2'-Indolylindolines undergo facile photooxidation to form symmetrica l fluorescent 2,2'-biindoles. The reaction proceeds slowly in air unde r ambient light, but direct irradiation facilitates the reaction. Pept ide and N-glycosylated substrates are compatible with this mild photoo xidation. Copyright (C) 1996 Elsevier Science Ltd