A NEW ONE-STEP METHOD FOR OXAADAMANTANE SYNTHESIS

Authors
KRASUTSKY PA KOLOMITSIN IV CARLSON RM JONES M
Citation
Pa. Krasutsky et al., A NEW ONE-STEP METHOD FOR OXAADAMANTANE SYNTHESIS, Tetrahedron letters, 37(32), 1996, pp. 5673-5674
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
32
Year of publication
1996
Pages
5673 - 5674
Database
ISI
SICI code
0040-4039(1996)37:32<5673:ANOMFO>2.0.ZU;2-I
Abstract
Oxidation of 2-methyl-2-hydroxyadamantane by trifluoroperacetic acid i n trifluoroacetic acid gives oxaadamantane and exo-2-oxaadamantane-4-o l in a good yield. Other 2-hydroxyadamantane derivatives do not underg o this transformation. An oxidative cleavage and subsequent cyclizatio n mechanism is proposed. Copyright (C) 1996 Elsevier Science Ltd