A NEW HIGHLY STEREOSELECTIVE MONOFLUORINATION IN BENZYLIC POSITION

Authors
KERMARREC C MADIOT V GREE D MEYER A GREE R
Citation
C. Kermarrec et al., A NEW HIGHLY STEREOSELECTIVE MONOFLUORINATION IN BENZYLIC POSITION, Tetrahedron letters, 37(32), 1996, pp. 5691-5694
Citations number
46
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
32
Year of publication
1996
Pages
5691 - 5694
Database
ISI
SICI code
0040-4039(1996)37:32<5691:ANHSMI>2.0.ZU;2-E
Abstract
Reaction of DAST with secondary alcohols vicinal to an arene Cr(CO)(3) unit gives with very high exo stereoselectivity the corresponding flu orides; the stereochemistry of the reaction appears to be exclusively controlled by the organometallic moiety. Copyright (C) 1996 Published by Elsevier Science Ltd