The performance of three hybrid membrane and distillation processes is
compared theoretically, using the separation of propylene and propane
as a representative case. For each system configuration the effect of
the main design variables is illustrated through parametric studies.
Results dealing with both design of new processes and retrofit of exis
ting distillation-based separation processes are presented. The result
s show qualitative trends which may serve as guidelines for design of
hybrid membrane and distillation processes. If the membrane is placed
parallel to the column, the optimal position for the membrane feed str
eam is close to the column feed plate, which represents a potential pi
nch point in the column. The optimal membrane cut rate for this config
uration is generally close to the molefraction of propylene in the mem
brane feed stream. The comparison of the systems performances indicate
s that placing the membrane in parallel or on the bottom stream of the
column gives the best performance of the hybrid process, both in term
s of compressor duty and in terms of installed membrane area.