DETERMINATION OF COPPER(II) BY ANODIC-STRIPPING VOLTAMMETRY USING A FLOW-THROUGH SYSTEM

Citation
A. Economou et Pr. Fielden, DETERMINATION OF COPPER(II) BY ANODIC-STRIPPING VOLTAMMETRY USING A FLOW-THROUGH SYSTEM, Analyst, 121(12), 1996, pp. 1903-1906
Citations number
15
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032654
Volume
121
Issue
12
Year of publication
1996
Pages
1903 - 1906
Database
ISI
SICI code
0003-2654(1996)121:12<1903:DOCBAV>2.0.ZU;2-D
Abstract
Copper(II) has been determined using anodic stripping voltammetry in a flow-through system, The working electrodes consisted of thin mercury films plated on a glassy carbon macrolectrode or microelectrode. Two flow-through cells, based on the wall-jet configuration and the thin-l ayer configuration, respectively, accommodated the working electrodes, Depending on the type of analysis, the flow system could operate on t he flow injection mode or continuous flow mode during the preconcentra tion period, The sequence of operations (mercury plating, metal precon centration, stripping and electrode cleaning) were remotely controlled , The procedures developed were applied to the quantification of Cu-II in different matrices (tap water, acidified sea-water and pharmaceuti cal tablets).