DETERMINATION OF TRACE AMOUNTS OF ALCOHOLS AND PHENOLS IN COMPLEX-MIXTURES AS FERROCENECARBOXYLIC ACID-ESTERS WITH GAS-CHROMATOGRAPHY ATOMIC-EMISSION DETECTION

Authors
ROLFES J ANDERSSON JT
Citation
J. Rolfes et Jt. Andersson, DETERMINATION OF TRACE AMOUNTS OF ALCOHOLS AND PHENOLS IN COMPLEX-MIXTURES AS FERROCENECARBOXYLIC ACID-ESTERS WITH GAS-CHROMATOGRAPHY ATOMIC-EMISSION DETECTION, Analytical communications, 33(12), 1996, pp. 429-432
Citations number
5
Categorie Soggetti
Chemistry Analytical
Journal title
Analytical communications → ACNP
ISSN journal
13597337
Volume
33
Issue
12
Year of publication
1996
Pages
429 - 432
Database
ISI
SICI code
1359-7337(1996)33:12<429:DOTAOA>2.0.ZU;2-C
Abstract
A method for the derivatization of phenols and alcohols with ferrocene carboxylic acid chloride to the corresponding esters is described, The esters are separated by capillary GC and detected by atomic emission in the iron-selective mode, thus ensuring detection limits of 150 fmol injected and high selectivity over non-iron-containing compounds, A c rude oil (Brent, North Sea) is used as an example, without any sample preparation before the derivatization, and is shown to contain approxi mately 1 mu mol phenols g(-1).