FACILE SYNTHESIS OF FUNCTIONALIZED NITROENAMINES .3. AMINOLYSIS OF 1-METHYL-5-NITROPYRIMIDIN-2(1H)-ONE

Authors
NISHIWAKI N TOHDA Y ARIGA M
Citation
N. Nishiwaki et al., FACILE SYNTHESIS OF FUNCTIONALIZED NITROENAMINES .3. AMINOLYSIS OF 1-METHYL-5-NITROPYRIMIDIN-2(1H)-ONE, Bulletin of the Chemical Society of Japan, 69(7), 1996, pp. 1997-2002
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
69
Issue
7
Year of publication
1996
Pages
1997 - 2002
Database
ISI
SICI code
0009-2673(1996)69:7<1997:FSOFN.>2.0.ZU;2-I
Abstract
The aminolysis of 1-methyl-5-nitropyrimidin-2(1H)-one furnished diimin es of nitromalonaldehyde in good yields. One of the imino groups of th e diimines was readily hydrolyzed on silica gel to give nitroenamines possessing a formyl group. These reagents behaved as the synthetic equ ivalent of unstable nitromalonaldehyde, affording azaheterocycles upon a treatment with hydrazines or diamines.