SUCCESSFUL ISOLATION AND X-RAY CRYSTAL-STRUCTURE OF (TRIS(N-L-RHAMNOSYL-2-AMINOETHYL)AMINE)(SULFATE) NICKEL(II) HYDRATE TRIMETHANOL SOLVATE- )(3)-TREN)(SO4)]CENTER-DOT-H2O-CENTER-DOT-3CH(3)OH

Citation
S. Yano et al., SUCCESSFUL ISOLATION AND X-RAY CRYSTAL-STRUCTURE OF (TRIS(N-L-RHAMNOSYL-2-AMINOETHYL)AMINE)(SULFATE) NICKEL(II) HYDRATE TRIMETHANOL SOLVATE- )(3)-TREN)(SO4)]CENTER-DOT-H2O-CENTER-DOT-3CH(3)OH, Inorganica Chimica Acta, 249(1), 1996, pp. 1-3
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00201693
Volume
249
Issue
1
Year of publication
1996
Pages
1 - 3
Database
ISI
SICI code
0020-1693(1996)249:1<1:SIAXCO>2.0.ZU;2-C
Abstract
We have succeeded in the isolation and X-ray crystal structure determi nation of the octahedral nickel(II) complex [Ni((L-Rha)(3)-tren) (SO4) ]. H2O . 3CH(3)OH (tren = tris(2-aminoethyl)amine; Rha = rhamnose) con taining an N-glycoside derived from the reaction of L-Rha and tren. Cr ystal data: C27H62N4O20SNi, M(r) = 853.56, orthorhombic, space group P 2(1)2(1)2(1), a = 16.035(4), b = 16.670(7), c = 15.38(1) Angstrom, Z = 4.