S. Yano et al., SUCCESSFUL ISOLATION AND X-RAY CRYSTAL-STRUCTURE OF (TRIS(N-L-RHAMNOSYL-2-AMINOETHYL)AMINE)(SULFATE) NICKEL(II) HYDRATE TRIMETHANOL SOLVATE- )(3)-TREN)(SO4)]CENTER-DOT-H2O-CENTER-DOT-3CH(3)OH, Inorganica Chimica Acta, 249(1), 1996, pp. 1-3
We have succeeded in the isolation and X-ray crystal structure determi
nation of the octahedral nickel(II) complex [Ni((L-Rha)(3)-tren) (SO4)
]. H2O . 3CH(3)OH (tren = tris(2-aminoethyl)amine; Rha = rhamnose) con
taining an N-glycoside derived from the reaction of L-Rha and tren. Cr
ystal data: C27H62N4O20SNi, M(r) = 853.56, orthorhombic, space group P
2(1)2(1)2(1), a = 16.035(4), b = 16.670(7), c = 15.38(1) Angstrom, Z =
4.