COMPLEXES OF BISMUTH(III) CHLORIDE WITH OXYGEN DONOR LIGANDS - STRUCTURAL CHARACTERIZATION OF BICL3-CENTER-DOT-3THF, BICL3 DIGLYME AND BICL3-CENTER-DOT-DIETHYLCARBITOL

Authors
EVELAND JR WHITMIRE KH
Citation
Jr. Eveland et Kh. Whitmire, COMPLEXES OF BISMUTH(III) CHLORIDE WITH OXYGEN DONOR LIGANDS - STRUCTURAL CHARACTERIZATION OF BICL3-CENTER-DOT-3THF, BICL3 DIGLYME AND BICL3-CENTER-DOT-DIETHYLCARBITOL, Inorganica Chimica Acta, 249(1), 1996, pp. 41-46
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
249
Issue
1
Year of publication
1996
Pages
41 - 46
Database
ISI
SICI code
0020-1693(1996)249:1<41:COBCWO>2.0.ZU;2-A
Abstract
The bismuth(III) chloride ether complexes BiCl3 . diglyme (1), BiCl3 . diethylcarbitol (2) and BiCl3 . 3THF (3) (diglyme = bis(2-methoxy)eth yl ether; diethylcarbitol = bis(2-ethoxy)ethyl ether) have been prepar ed. Compounds 1 and 2 form dimers in the solid state and exhibit disto rted pentagonal bipyramidal coordination around the bismuth centers, w hile complex 3 is monomeric in the crystal lattice and shows approxima te octahedral coordination for bismuth.