RHENIUM POLYHYDRIDES STABILIZED BY ARSINE LIGANDS

Authors
COSTELLO MT HARRIS TA WALTON RA
Citation
Mt. Costello et al., RHENIUM POLYHYDRIDES STABILIZED BY ARSINE LIGANDS, Inorganica Chimica Acta, 249(1), 1996, pp. 101-103
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
249
Issue
1
Year of publication
1996
Pages
101 - 103
Database
ISI
SICI code
0020-1693(1996)249:1<101:RPSBAL>2.0.ZU;2-D
Abstract
The mixed phosphine-arsine ligand Ph(2)PCH(2)CH(2)AsPh(2) (arphos) has been used to stabilize the rhenium polyhydrides Re2H8(arphos)(2) and ReH7 (arphos). The heptahydride is the first example of a compound of the type ReH(7)L(2) which contains a mixed phosphine-arsine donor set. The spectroscopic and electrochemical properties and stabilities of t hese complexes are described and compared with data for other complexe s of the types Re(2)H(8)L(4) and ReH(7)L(2).