[FE-2(SB2S6)(CO)(6)](2- A CATIONIC GROUP-15() )16 METAL CLUSTER/

Authors
DRAKE GW SCHIMEK GL KOLIS JW
Citation
Gw. Drake et al., [FE-2(SB2S6)(CO)(6)](2- A CATIONIC GROUP-15() )16 METAL CLUSTER/, Inorganic chemistry, 35(16), 1996, pp. 4534
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
16
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:16<4534:[ACG)M>2.0.ZU;2-B
Abstract
The first group 15/16 cationic metal complex [Fe-2(Sb2S6)(CO)(6)][SbF6 ](2) . 2SO(2) is formed when [S-8][Sb2F11](2) is reacted with 3 equiv of iron pentacarbonyl in liquid sulfur dioxide at room temperature. Th e cationic cluster is formed from an Sb2S6 cage capped on each end thr ough eta(1)-S, eta(2)-S-2 bound Fe(CO)(3) units. There is a center of inversion at the centroid position of the Sb2S6 cage. The antimony sou rce is apparently the starting anion [Sb2F11](-). This appears to be a n unprecedented example of the reaction of a cation with [Sb2F11](-).