COMPETITIVE ELECTROCHEMICAL THIOENYLATION AND SELENENYLATION OF CHLOROSILANES

Authors
JOUIKOV V GRIGORIEVA L
Citation
V. Jouikov et L. Grigorieva, COMPETITIVE ELECTROCHEMICAL THIOENYLATION AND SELENENYLATION OF CHLOROSILANES, Electrochimica acta, 41(15), 1996, pp. 2489-2491
Citations number
12
Categorie Soggetti
Electrochemistry
Journal title
Electrochimica acta → ACNP
ISSN journal
00134686
Volume
41
Issue
15
Year of publication
1996
Pages
2489 - 2491
Database
ISI
SICI code
0013-4686(1996)41:15<2489:CETASO>2.0.ZU;2-Z
Abstract
The anions PhS(-) and PhSe(-) obtained from cathodic reduction of dior ganodichalcogenides, substitute Cl in trimethylchlorosilane with relat ive rates k(Se)/k(S) = 9.3 to give trimethylsilylphenylsulfide and tri methylsilylphenylselenide; this reaction, carried out in the presence of a carbonyl compound, results in trimethylsilyl ethers of hemithio- (seleno-)ketals and acetals. Copyright (C) 1996 Elsevier Science Ltd